Mr. Tomasz Zieliński | Organic Chemistry | Innovative Research Award

Mr. Tomasz Zieliński | Organic Chemistry | Innovative Research Award

Mr. Tomasz Zieliński , Organic Chemistry, Nicolaus Copernicus University in Toruń , Poland

Tomasz Zielińsk , is an experienced chemical technologist with over 16 years in the refining and petrochemical industries. Working primarily at ORLEN S.A. in Płock, he’s contributed extensively to production technology, process optimization, and innovative projects enhancing refinery capacities by up to 40%. As an expert in alternative fuels and sustainable technologies, Tomasz serves on several national groups dealing with alternative fuels, climate regulations, and product quality. He’s currently pursuing a Ph.D. at Nicolaus Copernicus University in Toruń, focusing on innovative processes like microbiological hydrocarbon decomposition. With patented technology to produce valuable compounds like isopropanol and hydrogen, he envisions expanding synthetic fuel production to meet EU directives like RED III and Fit for 55. Known for analytical skills, innovative thinking, and leadership in project execution, Tomasz is a key figure driving technological transformation in Poland’s energy sector.

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Summary of Suitability for Award:

Developed a patented microbiological process for decomposing hydrocarbon residues into valuable compounds like isopropanol and hydrogen. Proposed using this technology to boost synthetic fuel production and hydrogen integration, contributing to EU climate goals. Successfully resolved critical fuel quality issues (Jet A-1, diesel), safeguarding production reliability and market reputation. Led projects implementing new fuel formulations (e.g. Efecta fuels), demonstrating practical innovation. Strong analytical skills, innovation mindset, project management, and cross-disciplinary collaboration. Demonstrated ability to translate complex research into real-world applications. Tomasz Zieliński’s track record of technological innovations, impactful problem-solving, and visionary research directions positions him as a very strong candidate for the “Innovative Research Award”. His unique blend of industrial experience, scientific research, and successful technology implementations aligns perfectly with the award’s purpose of recognizing groundbreaking contributions that advance industry and sustainability. His work has the potential to contribute significantly to cleaner fuels, process efficiency, and Europe’s climate goals, underscoring his innovative spirit and leadership in his field.

🎓Education:

Tomasz Zieliński’s educational path reflects his dedication to chemical technology and industrial safety. He began at the Zespół Szkół Centrum Edukacji in Płock, where he qualified as a Technician in Chemical Technology (2002-2006). He then earned his Bachelor’s degree in Chemical Technology (specializing in organic technology) at the Warsaw University of Technology (2006-2010). Continuing at the same university, he completed his Master of Engineering in Chemical Technology in 2012. Recognizing the importance of workplace safety, he pursued postgraduate studies in Occupational Health and Safety at the Cracow University of Technology in 2012-2013. Currently, he’s working toward a Ph.D. at Nicolaus Copernicus University in Toruń, diving deeper into innovative chemical processes and technologies. His diverse education equips him with technical expertise, research capabilities, and a keen understanding of industrial standards, crucial for leading advanced projects in the petrochemical sector.

🏢Work Experience:

Over 16 years, Tomasz Zieliński has built a robust career at ORLEN S.A., gaining hands-on and strategic experience. From 2004-2009, he undertook practical training on various installations like Catalytic Cracking, Olefins II, and butadiene production. Between 2009 and 2014, he worked as a Senior Process Operator on the Claus installation. From 2015 to mid-2023, he held the position of Senior Specialist in the Technology Office, tackling complex issues like diesel fuel stability and Jet A-1 fuel quality. Since July 2023, he’s been an Expert in the Project Coordination Team, overseeing efficiency, development, and revitalization projects. Notable achievements include resolving quality problems in fuels, leading technological trials for HVO blending, and coordinating large-scale innovation projects. His experience spans process optimization, analytical testing, project management, and implementation of new technologies, making him an essential contributor to refining and petrochemical advancements.

🏅Awards: 

Although specific official awards weren’t detailed in the CV text, Tomasz Zieliński’s professional record showcases significant achievements and recognition within ORLEN S.A. and the broader industry. His contributions have been acknowledged through leadership roles in critical projects, particularly resolving quality challenges in diesel and jet fuels and pioneering new fuel blends like Efecta. His patented technology for microbiological decomposition of residual hydrocarbons underscores his innovative drive and commitment to sustainability. Participation in national groups under POPIHN (Polish Organization of Oil Industry and Trade) reflects peer recognition of his expertise in alternative fuels, climate policy, and regulatory matters. His ongoing Ph.D. research also highlights academic pursuit and potential future honors. Tomasz’s career is marked by trust and respect from colleagues and industry leaders, testifying to his reputation as a talented, forward-thinking professional dedicated to technological progress and environmental responsibility.

🔬Research Focus:

Tomasz Zieliński’s research centers on sustainable energy and petrochemical innovation. His current Ph.D. work at Nicolaus Copernicus University explores microbiological decomposition of residual hydrocarbons, leading to production of isopropanol and hydrogen — crucial raw materials for petrochemical processes and synthetic fuels. His focus aligns with EU sustainability goals like RED III and Fit for 55, aiming to decarbonize fuel production and optimize refinery operations. Beyond his academic pursuits, Tomasz engages in practical projects, such as integrating hydrogen and synthetic fuel production into ORLEN’s infrastructure, utilizing innovative methods to maximize plant capacities. He’s deeply involved in evaluating fuel quality, blending biocomponents like HVO with diesel, and advancing new fuel formulations. His work bridges industrial application and scientific research, demonstrating how innovative technologies can drive energy transformation and secure Poland’s position in the evolving global energy market.

Publication Top Notes:

🧪 Synthesis of Silver Nanoparticles by Chemical Vapor Deposition Method and Its Application in Laser Desorption/Ionization Techniques

 

Prof. Safia TALEB | Organic Chemistry | Best Paper Award

Prof. Safia TALEB | Organic Chemistry | Best Paper Award

Prof. Safia TALEB , Organic Chemistry , Professor Dr. Senior Researcher at Djillali Liabès University, Algeria

Prof. Safia Taleb is a distinguished Algerian chemist, currently serving as Professor and Deputy Director at the Faculty of Exact Sciences, Department of Chemistry, D. Liabès University, Algeria. From 2010 to 2022, she was the Head of the Laboratory of Materials & Catalysis (LMC). She earned her Doctorate in Organic Chemistry from the Catholic University of Louvain (UCL), Belgium, in 1981, later obtaining Algerian equivalence. Prof. Taleb’s career has spanned decades, marked by leadership in research, education, and collaborative international publications. Her expertise includes organic and analytical chemistry, environmental remediation, wastewater treatment, and clay-based catalysis. She is actively engaged in sustainable science, focusing on recycling and water purification. With a prolific publication record and deep commitment to applied research, Prof. Taleb has made significant contributions to science and society, mentoring numerous students and fostering global partnerships in green chemistry and environmental innovation.

Professional Profile : 

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Summary of Suitability for Award:

Prof. Safia Taleb, a distinguished researcher and Professor of Chemistry at D. Liabes University, has made significant contributions in the fields of organic chemistry, water treatment, catalysis, and environmental sustainability. Her recent international publications display innovative and practical solutions to pressing environmental issues such as wastewater treatment, dye degradation, oil recycling, and humic acid removal. Her 2025 publication titled “Decoloration of Waste Cooking Oil by Maghnia Algerian Clays via Ion Exchange and Surface Adsorption” (published in Chem Engineering) is a strong candidate for the “Best Paper Award”, as Addresses a critical environmental concern—recycling waste cooking oil. Uses local and low-cost materials (Algerian clays) for sustainable solutions. Combines surface chemistry, materials science, and environmental engineering. Has global relevance and direct practical application, especially in developing regions. Prof. Taleb’s collaborative research approach with international and national scientists and her track record of impactful publications further bolster her candidacy. Prof. Safia Taleb’s research, particularly her 2025 paper in Chem Engineering, exemplifies the criteria of originality, scientific rigor, and environmental relevance sought in a “Best Paper Award”. Her extensive experience, commitment to solving real-world problems, and recent publication’s innovation make her a highly suitable candidate for this recognition.

🎓Education:

Prof. Safia Taleb’s academic journey began with a Baccalaureate in Applied Sciences (1970) in Mostaganem, Algeria. She pursued a Licence in Physical Sciences (Option: Chemistry) at the University of Es-Sénia, Oran, Algeria, graduating in 1974. A year later, in 1975, she earned a D.E.A. (Diplôme d’Études Approfondies) in Organic Chemistry from the same institution. Her pursuit of excellence led her abroad to the Catholic University of Louvain (UCL), Belgium, where she obtained her Doctorate Es Sciences in Organic Chemistry in 1981. In 1988, her Belgian Doctorate was officially recognized in Algeria through equivalence certification. Her solid educational foundation has empowered her pioneering contributions in organic synthesis, catalysis, and environmental science. Prof. Taleb’s international education and interdisciplinary focus continue to influence generations of Algerian scientists and innovators.

🏢Work Experience:

Prof. Safia Taleb has had a remarkable academic and research career spanning over four decades. Since 1989, she has served as Professor and Deputy Director at D. Liabès University, where she has been instrumental in curriculum development, research mentoring, and institutional management. From June 2010 to June 2022, she directed the Laboratory of Materials & Catalysis (LMC), driving innovation in sustainable materials and environmental technologies. Throughout her career, Prof. Taleb has led numerous national and international collaborations, particularly in wastewater treatment, clay-based adsorbents, and organic chemical analysis. She has authored and co-authored several peer-reviewed publications and supervised postgraduate research. Her leadership at LMC established it as a hub of applied chemistry in Algeria. An active contributor to environmental and analytical chemistry research, Prof. Taleb’s experience reflects an enduring dedication to scientific advancement and community well-being.

🏅Awards: 

While specific named awards are not listed in the provided data, Prof. Safia Taleb’s distinguished academic career reflects numerous professional recognitions. Her long-standing leadership at the Laboratory of Materials & Catalysis (LMC) and appointment as Deputy Director at D. Liabès University testify to institutional and peer recognition of her contributions. She has been regularly featured as lead or co-author in international journals, signaling esteem from the global scientific community. Her cross-border collaborations with researchers from Europe and North Africa have earned her recognition in Algeria and abroad. Additionally, her role in mentoring Ph.D. candidates, organizing research activities, and fostering innovations in environmental chemistry are indicative of her impact. Invitations to publish, collaborate, and lead reflect ongoing acknowledgment of her excellence and dedication in science and education.

🔬Research Focus:

Prof. Safia Taleb’s research bridges organic chemistry and analytical chemistry with environmental sustainability. Her core focus areas include wastewater treatment, natural clay materials, catalysis, bio-waste recycling, and water quality improvement. She is particularly renowned for developing adsorbent and catalytic materials from Algerian clays, applying them in the purification of industrial and domestic effluents. Her research is highly interdisciplinary, often merging chemistry, materials science, and environmental engineering to create eco-friendly solutions. Prof. Taleb is also engaged in valorization of agri-food waste, transforming it into functional materials for environmental applications. She employs spectroscopic, microbiological, and physicochemical techniques to characterize pollutants and evaluate remediation efficiency. Her recent work includes collaborative studies on the removal of synthetic dyes, treatment of olive mill wastewater, and recycling of used vegetable oils. Her research contributes significantly to Algeria’s environmental policy and global green chemistry initiatives.

Publication Top Notes:

1. Decoloration of Waste Cooking Oil by Maghnia Algerian Clays via Ion Exchange and Surface Adsorption

2. Temperature and pH Influence on Diuron Adsorption by Algerian Mont-Na Clay

3. Combined Ozonation Process and Adsorption onto Bentonite Natural Adsorbent for the o-Cresol Elimination

4. High Adsorption Capacity of Thermally Treated Solid Olive Wastes to Treat Olive Mill Wastewater

5. Heterogeneous Catalytic Degradation of Diuron Using Algerian Sodium Montmorillonite

6. Variation of Used Vegetable Oils’ Composition upon Treatment with Algerian Clays

7. Performance of NF90 and NF270 Commercial Nanofiltration Membranes in the Defluoridation of Algerian Brackish Water

Citations: 17

8. Preparation, Characterization and Application of Fe-Pillared Bentonite to the Removal of Coomassie Blue Dye from Aqueous Solutions

9. Lead and cadmium removal by adsorption process using hydroxyapatite porous materials

10. Mechanism study of metal ion adsorption on porous hydroxyapatite: experiments and modeling

 

 

Assist. Prof. Dr. Mohammad Taghi Nazeri | Organic Chemistry | Best Researcher Award

Assist. Prof. Dr. Mohammad Taghi Nazeri | Organic Chemistry | Best Researcher Award

Assist. Prof. Dr. Mohammad Taghi Nazeri , Shahid Beheshti University, Iran

Dr. Mohammad Taghi Nazeri, born in Qazvin, Iran, is a distinguished faculty member at Shahid Beheshti University, Tehran. He earned his Ph.D. under the mentorship of Prof. Ahmad Shaabani, followed by a postdoctoral fellowship in the same research group. With a robust academic portfolio, he focuses on the synthesis of bioactive compounds, multicomponent reactions, and material functionalization. Dr. Nazeri has authored over 40 impactful papers and reviews, showcasing his expertise in organic chemistry. His innovative approaches to green chemistry and sustainable synthesis have garnered recognition in the scientific community, contributing significantly to advancements in pseudopeptidic and heterocyclic chemistry.

Professional Profile:

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Summary of Suitability for Award:

Dr. Mohammad Taghi Nazeri exemplifies the qualities of an outstanding researcher, making him a strong candidate for the “Best Researcher Awards.” With a focus on sustainable synthesis and green chemistry, Dr. Nazeri has significantly advanced the field of organic chemistry, particularly in isocyanide-based multicomponent reactions and pseudopeptidic compound synthesis. His innovative methodologies emphasize eco-friendly processes, reflecting a commitment to addressing global sustainability challenges.Dr. Nazeri’s exceptional research achievements, innovative methodologies, and contributions to advancing sustainable chemistry establish him as a deserving recipient of the “Best Researcher Awards.” His work not only enriches the academic community but also addresses pressing environmental and societal challenges, making him an exemplary model of scientific excellence and impactful research.

🎓Education:

Dr. Nazeri completed his M.Sc. in organic chemistry at Tehran University, where he cultivated his foundational expertise in chemical sciences. He pursued his Ph.D. at Shahid Beheshti University, specializing in advanced multicomponent reactions and pseudopeptidic compounds under the guidance of Prof. Ahmad Shaabani. His doctoral work revolved around designing efficient, sustainable synthetic pathways for bioactive heterocycles. Building upon this, Dr. Nazeri undertook a postdoctoral fellowship at Shahid Beheshti University, further refining his expertise in green chemistry and material functionalization. His educational journey reflects a commitment to developing innovative solutions for complex synthetic challenges, integrating sustainability and efficiency.

🏢Work Experience:

Dr. Nazeri began his academic career with extensive research in isocyanide-based multicomponent reactions, focusing on the synthesis of heterocyclic compounds and pseudopeptides. After earning his Ph.D., he joined Prof. Ahmad Shaabani’s research group for postdoctoral studies, emphasizing sustainable chemistry. Since 2022, he has been a faculty member at Shahid Beheshti University, where he teaches, mentors students, and leads groundbreaking research projects. His contributions include developing eco-friendly synthetic methodologies and functionalizing materials for applications in green catalysis and CO₂ fixation. With over 40 publications, Dr. Nazeri’s experience showcases his innovative approach to organic chemistry and materials science.

🏅Awards: 

Dr. Nazeri has received widespread recognition for his contributions to organic chemistry. His awards highlight excellence in green chemistry and multicomponent reactions, showcasing his innovative approach to sustainable synthesis. His postdoctoral fellowship, under the esteemed guidance of Prof. Ahmad Shaabani, reflects his exceptional research capabilities. Dr. Nazeri’s work has earned accolades from the scientific community, underscoring his commitment to advancing eco-friendly methodologies. His role as a faculty member at Shahid Beheshti University further attests to his impact in shaping the next generation of researchers in organic chemistry.

🔬Research Focus:

Dr. Nazeri’s research interests include the design and synthesis of bioactive compounds through novel multicomponent reactions, with a particular emphasis on pseudopeptidic and heterocyclic scaffolds. He explores sustainable methods for the functionalization and modification of materials, employing green chemistry principles. His work focuses on isocyanide-based reactions in water, aiming to create efficient synthetic routes for medicinally relevant compounds. Dr. Nazeri also investigates applications in CO₂ fixation and antibacterial nanocomposites, contributing to eco-friendly advancements in materials science. His research bridges organic synthesis, green catalysis, and material functionalization for sustainable development.

Publication Top Notes:

5-Amino-pyrazoles: potent reagents in organic and medicinal synthesis

Authors: A. Shaabani, M.T. Nazeri, R. Afshari

Citations: 78

Year: 2019

Multicomponent reactions as a potent tool for the synthesis of benzodiazepines

Authors: H. Farhid, V. Khodkari, M.T. Nazeri, S. Javanbakht, A. Shaabani

Citations: 67

Year: 2021

Cyclic imines in Ugi and Ugi-type reactions

Authors: M.T. Nazeri, H. Farhid, R. Mohammadian, A. Shaabani

Citations: 57

Year: 2020

Deep eutectic solvent as a highly efficient reaction media for the one-pot synthesis of benzo-fused seven-membered heterocycles

Authors: A. Shaabani, S.E. Hooshmand, M.T. Nazeri, R. Afshari, S. Ghasemi

Citations: 46

Year: 2016

Green one-pot synthesis of multicomponent-crosslinked carboxymethyl cellulose as a safe carrier for the gentamicin oral delivery

Authors: S. Javanbakht, M.T. Nazeri, A. Shaabani, M. Ghorbani

Citations: 40

Year: 2020

5-aminopyrazole-conjugated gelatin hydrogel: A controlled 5-fluorouracil delivery system for rectal administration

Authors: M.T. Nazeri, S. Javanbakht, A. Shaabani, M. Ghorbani

Citations: 38

Year: 2020

An efficient one-pot, regio-and stereoselective synthesis of novel pentacyclic-fused pyrano[3,2,c] chromenone or quinolinone benzosultone derivatives in water

Authors: M. Ghandi, M.T. Nazeri, M. Kubicki

Citations: 35

Year: 2013

Multi‐component reaction‐functionalized chitosan complexed with copper nanoparticles: An efficient catalyst toward A3 coupling and click reactions in water

Authors: A. Shaabani, M. Shadi, R. Mohammadian, S. Javanbakht, M.T. Nazeri

Citations: 34

Year: 2019

Isocyanide-based multicomponent reactions in water: Advanced green tools for the synthesis of heterocyclic compounds

Authors: T. Nasiriani, S. Javanbakht, M.T. Nazeri, H. Farhid, V. Khodkari, A. Shaabani

Citations: 33

Year: 2022

Synthesis of polysubstituted pyrroles via isocyanide-based multicomponent reactions as an efficient synthesis tool

Authors: M.T. Nazeri, A. Shaabani

Citations: 32

Year: 2021

 

 

 

 

Prof . Dmitry Dar’in | Organic Chemistry Award | Best Researcher Award

Prof . Dmitry Dar’in | Organic Chemistry Award | Best Researcher Award

Prof . Dmitry Dar’in  , Saint Petersburg State University, Institute of Chemistry, Russia 

Prof. Dmitry Dar’in is a distinguished chemist at the Institute of Chemistry, Saint Petersburg State University, with over 20 years of academic and research expertise. He is widely recognized for his work in heterocyclic chemistry and organic synthesis, actively supervising more than 20 graduate students. Prof. Dar’in has significantly advanced research in the synthesis of polysubstituted lactams and diazo compounds, expanding the boundaries of diazo chemistry and multicomponent reactions. With a robust publication record, including 236 Scopus-indexed articles, he has made remarkable contributions to targeted protein degradation, antitubercular agents, and trace amine-associated receptor studies. His dedication to scientific collaboration is evident in his partnerships with top international researchers, including Prof. Ewgenij Proschak, Prof. Saeed Balalaie, and Dr. Marcus D. Hartmann. He also serves as a Guest Editor for the journal Molecules on the “Diazo Chemistry” special issue. Prof. Dar’in is an influential figure in modern chemistry, continually driving innovation and education.

Professional Profile:

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Summary of Suitability for Award:

Prof. Dmitry Dar’in is exceptionally suited for the “Best Researcher Award” due to his impactful contributions to the fields of diazo chemistry, heterocyclic compounds, and multicomponent reactions. With over 20 years of experience and an extensive portfolio of 236 Scopus-indexed publications, his work has significantly influenced organic synthesis, particularly in developing innovative methodologies for diazo compound synthesis in aqueous media and expanding the Castagnoli-Cushman reaction’s applications. His high citation index (h-index of 23) reflects the relevance and quality of his research contributions, demonstrating a consistent commitment to advancing chemical science.

🎓Education:

Prof. Dmitry Dar’in has pursued an extensive educational journey focused on chemistry, culminating in his expertise in heterocyclic compounds and organic synthesis. He completed his initial studies at a reputed university, where he laid a strong foundation in chemical theory and application. Further advancing his knowledge, Prof. Dar’in specialized in heterocyclic and diazo chemistry, undertaking advanced research projects and collaborative studies that have become foundational to his career. His formal education was complemented by ongoing research, allowing him to gain hands-on experience with complex chemical reactions and synthesis methodologies. Prof. Dar’in has continued his professional development through interactions with prominent research groups worldwide, which have enriched his teaching and research endeavors. His education paved the way for his current role as a professor and researcher, where he imparts deep knowledge in organic synthesis and continues to explore innovative approaches in chemistry.

🏢Work Experience:

With over two decades of experience in academic and applied research, Prof. Dmitry Dar’in has established himself as a leader in heterocyclic chemistry and diazo compound synthesis. He teaches advanced courses on heterocyclic chemistry and organic synthesis at Saint Petersburg State University, where he has also supervised over 20 graduate theses, guiding students in cutting-edge research methodologies. Prof. Dar’in’s experience spans multiple successful projects, including five current research endeavors and two consultancy projects for industry partners. His expertise is further reflected in his role as Guest Editor for Molecules, where he oversees specialized issues on diazo chemistry. Prof. Dar’in has extensive international collaboration experience, working closely with esteemed scientists like Prof. Ewgenij Proschak and Prof. Saeed Balalaie. His global engagements and dedication to advancing chemistry research continue to influence modern synthetic methods and applications, particularly in medicinal chemistry and targeted protein degradation.

🏅Awards:

Prof. Dmitry Dar’in has received several prestigious awards in recognition of his innovative contributions to chemistry, particularly in the areas of heterocyclic compounds and diazo chemistry. His groundbreaking work has earned him the respect of both academic and industrial circles, where his methods for synthesizing diazo compounds in aqueous environments and his contributions to the Castagnoli-Cushman reaction have been particularly celebrated. His scholarly excellence is also recognized through his editorial role for Molecules, showcasing his influence in shaping modern research directions. In addition to these honors, Prof. Dar’in has been acknowledged for his collaborative work with international research leaders, reflecting his commitment to global scientific advancement. His contributions to the field, both in education and research, have earned him nominations for top-tier awards such as the Best Researcher Award, emphasizing his stature as a leading scientist in organic synthesis and multicomponent reactions.

🔬Research Focus:

Prof. Dmitry Dar’in’s research primarily explores diazo chemistry, heterocyclic compounds, and multicomponent reactions. He has pioneered efficient synthesis methods for diazo compounds, especially diazo metanesulfonamides, and has introduced aqueous medium diazo transfer techniques, which have expanded the practical applications of these compounds. His work with polysubstituted lactams through the Castagnoli-Cushman reaction has unlocked new pathways for using cyclic anhydrides and imine-type reagents. Prof. Dar’in’s research also delves into targeted protein degradation, trace amine-associated receptors, and antitubercular agents, making substantial strides in medicinal chemistry. His innovative approaches to synthesizing five- and six-membered diazo heterocycles have opened avenues for further exploration in core functionalization and heterocyclic frameworks. Prof. Dar’in’s research remains at the forefront of organic chemistry, impacting both theoretical knowledge and practical applications in pharmaceutical sciences.

Publication Top Notes:

  • Title: Synthesis of cyclic sulfamides via one-pot alkylation/aza-Michael cascade reaction
  • Title: Coinage (Au, Ag, Cu) metal-catalyzed (3 + 2) annulation of α-aminoketones and electron-deficient alkynes as a route to 3-EWG-substituted pyrroles
    • Citations: 1
  • Title: Diazo Tetramic Acids Provide Access to Natural-Like Spirocyclic Δα,β-Butenolides through Rh(II)-Catalyzed O-H Insertion/Base-Promoted Cyclization
    • Citations: 6
  • Title: The synthesis of 1-oxa-9-azaspiro[5.5]undecane derivatives and optimization of antituberculosis activity thereof
  • Title: Phosphorescent Cyclometalated Palladium(II) and Platinum(II) Complexes Derived from Diaminocarbene Precursors